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臭氧曝氣對厭氧處理豬場廢水磷素形態(tài)的影響
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“十二五”國家科技支撐計劃資助項目(2012BAD15B02)和天津市科技支撐計劃重點項目(12ZCZDNC01800)


Influence of Ozone Disinfection on Phosphorus Form Transformation in Anaerobic Swine Wastewater
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    摘要:

    應用自行設計的臭氧深度處理裝置對豬場厭氧處理廢水開展曝氣試驗,在曝氣0、10、20、40、60min時分別取樣測定各種形態(tài)磷素質(zhì)量濃度。結(jié)果表明,臭氧不同曝氣時間對廢水體系(液體和固體)中磷素形態(tài)有顯著影響。可溶性總磷、可溶性無機磷、總有機磷和顆粒態(tài)有機磷質(zhì)量濃度呈下降趨勢,60min取樣時分別比初始減少30.28%、41.80%、34.92%和79.53%,均達到顯著性差異水平(P<0.05);可溶性有機磷、顆粒態(tài)總磷、顆粒態(tài)無機磷質(zhì)量濃度呈上升趨勢,60min取樣時分別比初始增加105.11%、46.74%和123.86%,均達到顯著性差異水平(P<0.05)。60min內(nèi)通過磷化氫氣態(tài)途徑損失量極小,僅占廢水體系總磷量的0.38%。廢水體系中的總磷質(zhì)量濃度基本保持不變。經(jīng)臭氧消毒準備用于農(nóng)田的豬場廢水應考慮易被植物利用的速效磷的損失以及顆粒態(tài)磷素的回收。

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    As a kind of advanced oxidation technology, ozone aeration has been widely used in wastewater treatment and disinfection. Ozone aeration of piggery wastewater also significantly affects the forms of phosphorus and effectiveness, which have important effects on the utilization of pigfarm effluent regeneration in farmland. In order to study the influences of different durations of ozone aeration on the phosphorus content and form transformation in anaerobic swine wastewater, the experiment, sampling and measuring the content of phosphorus in different forms, was conducted on self designed apparatus, with five different durations of ozone aeration, 0min, 10min, 20min, 40min, 60min, respectively. The results show that different durations of ozone aeration remarkably affect the content of phosphorus in different forms in wastewater system. Specifically, the contents of total soluble phosphorus, soluble inorganic phosphorus, total organic phosphorus and particulate organic phosphorus show decline trends with the magnitudes of 30.28%, 41.80%, 34.92% and 79.53% at the end of aeration lasted for 60min, respectively. By the contrary, the contents of soluble organic phosphorus, total particulate phosphorus and particulate inorganic phosphorus show upward trend, which increase by 105.11%, 46.74% and 123.86% at the end of 60min (P<0.05), respectively. Meanwhile, the loss of gaseous phosphorus is also detected in the absorbing liquid with trace amount, which only occupying 0.38% of the total phosphorus. The total phosphorus content in the wastewater system is basically unchanged. The loss of available phosphorus and the recovery of particulate phosphorus in the swine wastewater after ozone aeration should be taken into consideration.

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王 風,張 月,薛長亮,石亞楠,張克強,張龍江.臭氧曝氣對厭氧處理豬場廢水磷素形態(tài)的影響[J].農(nóng)業(yè)機械學報,2014,45(7):151-155. Wang Feng, Zhang Yue, Xue Changliang, Shi Ya’nan, Zhang Keqiang, Zhang Longjiang. Influence of Ozone Disinfection on Phosphorus Form Transformation in Anaerobic Swine Wastewater[J]. Transactions of the Chinese Society for Agricultural Machinery,2014,45(7):151-155.

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  • 收稿日期:2013-09-08
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  • 在線發(fā)布日期: 2014-07-10
  • 出版日期: 2014-07-10