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牛奶含水率介電譜結(jié)合化學計量學檢測方法
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國家自然科學基金項目(31671935)和江蘇省農(nóng)產(chǎn)品物理加工重點實驗室開放基金項目(JAPP2014-2)


Detecting Moisture Content of Cow’s Milk Using Dielectric Spectra and Chemometrics
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    摘要:

    為了實現(xiàn)牛奶含水率的快速檢測,采用網(wǎng)絡分析儀和同軸探頭測量了室溫((25±05)℃)下20~4500MHz間105個牛奶樣品的相對介電常數(shù)和介質(zhì)損耗因子。發(fā)現(xiàn)基于單一頻率下的介電參數(shù)很難預測牛奶的含水率。為此,將介電譜與化學計量學方法相結(jié)合預測牛奶的含水率?;赬-Y共生距離法進行了樣本集劃分,得到校正集樣本75個和預測集樣本30個。采用連續(xù)投影算法從全介電譜中提取出了15個用于預測牛奶含水率的特征變量;建立了基于全介電譜和連續(xù)投影算法提取的特征變量預測牛奶含水率(87.28%~91.30%)的廣義神經(jīng)網(wǎng)絡、支持向量機和極限學習機模型。結(jié)果發(fā)現(xiàn),基于連續(xù)投影算法提取的特征變量所建立的極限學習機模型是預測牛奶含水率的最優(yōu)模型,其預測相關(guān)系數(shù)、預測均方根誤差和剩余預測偏差分別為0.988、0.119%和6.723。研究表明,介電譜結(jié)合化學計量學方法可用于檢測牛奶的含水率。

    Abstract:

    To explore a rapid method for detecting moisture content of cow’s milk, a network analyzer and an openended coaxialline probe were applied to measure the dielectric properties (relative dielectric constant and dielectric loss factor) of 105 milk samples over the frequency range of 20~4500MHz at room temperature (25±0.5)℃. The low linear correlation coefficient between the moisture content and the permittivities at a single frequency of used milk samples showed that it was difficult to predict the moisture content of milk using a single permittivity value. Therefore, the dielectric spectra combined with chemometrics were used to determine the moisture content of milk. All samples were partitioned into calibration set (75 samples) and prediction set (30 samples) by using set partitioning method based on joint X-Y distances. Fifteen characteristic variables that predicting moisture content of cow’s milk were selected by successive projection algorithm from full spectra. The generalized regression neural network, support vector machine and extreme learning machine models were established to predict moisture content of milk (87.28%~91.30%), based on the original full dielectric spectra and characteristic variables. The results showed that the extreme learning machine model established using the characteristic variables selected by successive projection algorithm was the best model in determining moisture content of milk, with the correlation coefficient of prediction, rootmeansquare error of prediction, and residual prediction deviation of 0.988, 0.119%, and 6.723, respectively. The study indicates that the dielectric spectra combined with chemometrics could be used to detect moisture content of milk. The research is helpful to develop a new milk moisture detector which could be used in situ or online detection.

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郭文川,林碧瑩.牛奶含水率介電譜結(jié)合化學計量學檢測方法[J].農(nóng)業(yè)機械學報,2016,47(9):249-255. Guo Wenchuan, Lin Biying. Detecting Moisture Content of Cow’s Milk Using Dielectric Spectra and Chemometrics[J]. Transactions of the Chinese Society for Agricultural Machinery,2016,47(9):249-255.

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  • 收稿日期:2016-06-01
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  • 在線發(fā)布日期: 2016-09-10
  • 出版日期: 2016-09-10