亚洲一区欧美在线,日韩欧美视频免费观看,色戒的三场床戏分别是在几段,欧美日韩国产在线人成

羥丙基甲基纖維素高吸水性樹脂制備與性能表征
作者:
作者單位:

作者簡介:

通訊作者:

中圖分類號:

基金項目:

公益性行業(yè)(農(nóng)業(yè))科研專項(201503137)


Preparation and Performance Characterization of Hydroxypropyl Methyl Cellulose Based Super Absorbent Resin
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 圖/表
  • |
  • 訪問統(tǒng)計
  • |
  • 參考文獻(xiàn)
  • |
  • 相似文獻(xiàn)
  • |
  • 引證文獻(xiàn)
  • |
  • 資源附件
  • |
  • 文章評論
    摘要:

    以羥丙基甲基纖維素為骨架材料,丙烯酸為接枝共聚單體,過硫酸銨-亞硫酸氫鈉為引發(fā)劑,聚乙二醇200二丙烯酸酯為交聯(lián)劑,在微波輻射的條件下通過接枝聚合反應(yīng)制備高吸水性樹脂,并對高吸水性樹脂的吸液倍率、吸液速率、保水性能以及紅外光譜、熱穩(wěn)定性、表觀形態(tài)進(jìn)行表征。結(jié)果表明,羥丙基甲基纖維素與丙烯酸質(zhì)量比為1/7、中和度為65%、引發(fā)劑與丙烯酸質(zhì)量分?jǐn)?shù)為1%、交聯(lián)劑與丙烯酸質(zhì)量分?jǐn)?shù)為0.4%、反應(yīng)時間為4.5min是較優(yōu)的制備方法,該條件下制備的羥丙基甲基纖維素高吸水性樹脂吸水倍率可達(dá)497.13g/g,吸鹽倍率為61.70g/g;35℃條件下,該高吸水性樹脂可保水48h以上;重復(fù)使用6次后,該高吸水性樹脂仍具有較高的吸液倍率。

    Abstract:

    Super absorbent resin was prepared by graft copolymerization of hydroxypropyl methylcellulose (HPMC) with acrylic acid as graft copolymer, ammonium persulfatesodium bisulfite as initiator and polyethylene glycol diacrylate as crosslinker under microwave radiation. The absorbent ratio, absorbent rate and crosslinking rate of super absorbent resin were studied. The water retention properties and IR spectra, thermogravimetric and apparent morphology were characterized. The results showed that the optimum preparation methods were as follows:the mass ratio of HPMC to acrylic acid was 1/7, the neutralization degree was 65%, the mass ratio of initiator to acrylic acid was 1%, the mass ratio of crosslinking agent to acrylic acid was 0.4%, and the reaction time was 4min and 30s. Under the optimum preparation conditions, the water absorption ratio of HPMC super absorbent resin could reach 497.13g/g and the salt absorption ratio was 61.70g/g. This hydroxypropyl methyl cellulose based super absorbent resin could absorb liquid to reach the state of preservation in 30min quickly. The super absorbent resin could retain water for more than 48h at 35℃, 6h at 55℃ and 5h at 75℃. After six times of reuse, the water absorption rate of the super absorbent resin could still reach 69.7% of the initial water absorption rate, and the salt absorption rate could still reach 44.2% of the initial salt absorption rate. The super absorbent resin had good reusability. Thermogravimetric analysis showed that the super absorbent resin had good stability at 330℃. The hydroxypropyl methyl cellulose based super absorbent resin had good water absorption, salt resistance, high water retention rate and excellent reusability.

    參考文獻(xiàn)
    相似文獻(xiàn)
    引證文獻(xiàn)
引用本文

王宇欣,李雪嫄,趙亞楠,王平智.羥丙基甲基纖維素高吸水性樹脂制備與性能表征[J].農(nóng)業(yè)機(jī)械學(xué)報,2019,50(2):297-306. WANG Yuxin, LI Xueyuan, ZHAO Ya’nan, WANG Pingzhi. Preparation and Performance Characterization of Hydroxypropyl Methyl Cellulose Based Super Absorbent Resin[J]. Transactions of the Chinese Society for Agricultural Machinery,2019,50(2):297-306.

復(fù)制
分享
文章指標(biāo)
  • 點擊次數(shù):
  • 下載次數(shù):
  • HTML閱讀次數(shù):
  • 引用次數(shù):
歷史
  • 收稿日期:2018-11-05
  • 最后修改日期:
  • 錄用日期:
  • 在線發(fā)布日期: 2019-02-10
  • 出版日期:
文章二維碼