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基于載La半焦基催化的松木熱解試驗(yàn)
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國家自然科學(xué)基金項(xiàng)目(51768054、51764044)、內(nèi)蒙古自治區(qū)科技創(chuàng)新引導(dǎo)項(xiàng)目(KCBJ2018077)、內(nèi)蒙古自然科學(xué)基金項(xiàng)目(2017MS(LH)0524)和內(nèi)蒙古應(yīng)用技術(shù)研究與開發(fā)計(jì)劃項(xiàng)目(20180823)


Experiment on Pine Pyrolysis Based on Semi-coke Catalyzed by La
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    摘要:

    采用浸漬法,以松木熱解半焦為載體,制備了載La半焦基催化劑,利用自行設(shè)計(jì)的兩段式生物質(zhì)催化熱解固定床反應(yīng)系統(tǒng)進(jìn)行松木燃料棒催化熱解試驗(yàn),研究不同重整溫度下載La半焦基催化劑對生物質(zhì)熱解氣、焦油、焦炭三相產(chǎn)物的影響規(guī)律。通過氣體組分的變化、焦油FTIR譜圖的變化以及催化劑SEM、XRD表征特性測試,探討載La半焦基催化劑對生物質(zhì)熱解催化重整效果隨溫度的變化規(guī)律,并與無催化劑和以半焦為催化劑的催化性能進(jìn)行對比。試驗(yàn)表明:催化重整溫度為800℃、La負(fù)載量為6%時(shí),半焦基催化劑性能較好,經(jīng)載La半焦基催化劑催化重整后,松木熱解氣最高產(chǎn)率達(dá)到531g/kg,焦油生成量最少,為90g/kg;H2體積分?jǐn)?shù)由650℃時(shí)的20.42%升高至850℃時(shí)的32.66%,相較于無催化劑和半焦催化劑條件,載La半焦基催化劑在800℃時(shí)H2體積分?jǐn)?shù)明顯高于無催化劑時(shí)的16.77%和以半焦為催化劑時(shí)的20.06%;焦油生成量降低趨勢明顯;經(jīng)催化重整后,催化劑存在金屬元素的團(tuán)聚現(xiàn)象,活性組分La2O2CO3和La轉(zhuǎn)化為La2O3,伴隨著積碳、積灰堵塞催化劑表面部分孔道,催化活性有所減弱。研究表明,載La半焦基催化劑表現(xiàn)出較好的松木催化熱解性能。

    Abstract:

    The pine pyrolysis semi-coke was used as the carrier, and the La-loaded semi-coke based catalyst was prepared by the impregnation method. The self-constructed two-stage pyrolysis furnace was used as the test platform to conduct the pine fuel rod catalytic pyrolysis test. The changes of three-phase products of biomass pyrolysis gas, tar, and coke with La-loaded semi-coke based catalysts at different reforming temperatures were studied. Through the change of gas composition, the change of FTIR spectrum of tar, and the characterization of SEM and XRD of the catalyst, the variation of temperature of La-loaded semi-coke based catalyst on the pyrolysis and reforming effect of biomass with temperature was discussed, and compared with the catalytic performance of catalyst-free and semi-coke as catalyst. The results showed that semi-coke based catalysts with a supported La content of 6% had better performance. When the catalytic reforming temperature was 800℃, the maximum yield of pine pyrolysis gas was 531g/kg, and the lowest tar production was 90g/kg after catalytic reforming with La-loaded semi-coke based catalyst. The H2 volume fraction was increased from 20.42% at 650℃ to 32.66% at 850℃. Compared with the conditions without catalyst and semi-coke catalyst, its H2 volume fraction at 800℃ was significantly higher than 16.77% without catalyst and 20.06% with semi-coke as catalyst. The amount of tar production was significantly reduced. After catalytic reforming, agglomeration of metal elements existed in the catalyst, and the active components La2O2CO3 and La were converted to La2O3. With the carbon and ash deposits blocking some pores on the catalyst surface, the catalytic activity was weakened. The results showed that La-loaded semi-coke based catalyst had good catalytic performance for pine pyrolysis.

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牛永紅,張駿,蔡堯堯,王文才,李義科,楊占峰.基于載La半焦基催化的松木熱解試驗(yàn)[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2021,52(1):286-293. NIU Yonghong, ZHANG Jun, CAI Yaoyao, WANG Wencai, LI Yike, YANG Zhanfeng. Experiment on Pine Pyrolysis Based on Semi-coke Catalyzed by La[J]. Transactions of the Chinese Society for Agricultural Machinery,2021,52(1):286-293.

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  • 收稿日期:2020-02-22
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  • 在線發(fā)布日期: 2021-01-10
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